MINISTRY OF TRANSPORT OF THE RUSSIAN FEDERATION
AGREED APPROVED by the State Committee of the Ministry of Transport of the Russian Federation of the Russian Federation for Environmental Protection 28 10 1998 and Hydrometeorology 26 08 98 No. 05-12/16-389METHODOLOGY
conducting an inventory of emissions of pollutants into the atmosphere for asphalt concrete plants
(by calculation method)
The preparation of the 2nd revised and supplemented edition of this Methodology was attended by: Ph.D. Donchenko V. V., Ph.D. Manusadzhyants Zh. G., Samoilova L. G., Solntseva G. Ya. (NIIAT), Ph.D. n. Mazepova V. I., Bobkov V. V., Berezhnaya Yu. A. (NPO RosdorNII).
INTRODUCTION
This methodology was developed by order of the Ministry of Transport Russian Federation and is designed to provide methodological assistance to employees of operating asphalt concrete plants (APC) in conducting an inventory of pollutant emissions, developing draft standards for maximum permissible emissions (MAE), environmental passports, determining the level of impact of individual emission sources on the state of the air, forecasting the magnitude of emissions in the future.1. GENERAL PROVISIONS
The methodology establishes the procedure for calculating emissions of pollutants from technological equipment installed on the territory of the asphalt plant. As a rule, in addition to the main technological equipment for the preparation of asphalt concrete and the preparation of mineral and binder materials, numerous sites are located on the territory of the asphalt plant, the products of which are used in the construction and repair work in the road industry. The main purpose of the inventory of pollutants is to obtain initial data for: environment(atmospheric air); - development of draft standards for emissions of pollutants into the atmosphere both from the asphalt plant as a whole and for individual sources of air pollution; - organization of control over compliance with established standards for emissions of pollutants into the atmosphere; - assessment of the environmental characteristics of technologies used at the asphalt plant; - planning of air protection works at the asphalt plant. The calculation of gross and maximum single emissions of pollutants is carried out using specific indicators, i.e. the amount of emitted pollutants, reduced to units of time, equipment. mass of consumable materials. Specific indicators of pollutant emissions from production sites are given on the basis of the results of studies and observations carried out by various research and design institutes. The work on the calculation of pollutant emissions is carried out by the asphalt plant either on its own or attracts a specialized organization for this. licensed to carry out such work. If calculations of pollutant emissions are carried out by a specialized organization, then it must require the asphalt plant to provide data on the actual quantity and type of equipment, the quantity and grades of materials used, the number of days of operation per year for each piece of equipment and its net operating time per day. ABS is responsible for the completeness and reliability of the inventory data. Calculation of emissions from asphalt plants should be carried out on the basis of the actual technical characteristics of this mixer. In the Methodology, for reference, specifications for asphalt concrete plants, released earlier and constituting the main fleet in road organizations.2. SOURCES OF POLLUTANT EMISSIONS AT ASPHALT CONCRETE PLANTS
The industrial site of the asphalt plant, as a rule, includes workshops for the preparation of organic binder and asphalt concrete, the preparation of mineral materials, and boiler houses. Often, shops for the preparation of road viscous bitumen from raw materials (tar), bitumen emulsions, reinforced soils, stone crushing and screening plants are also located here. ABZ can be equipped with sets of equipment of the following types: D-597. D-597A, D-508-2A, D-617. D-645-2. DS-117-2K (2E), DS-1895, D-158, "Teltomat" made in Germany and other imported asphalt mixing plants/capacity 25, 32-42, 50, 100 and 200 t/h. Sources of air pollution are divided into sources of emission and sources of emissions of pollutants into the atmosphere. Sources of pollutant emission are: technological unit, installation, device, apparatus, etc., emitting pollutants during operation. Sources of pollutant emissions are: a pipe, an aeration lamp, a bunker, a ventilation shaft, a manhole, etc. devices that release pollutants into the atmosphere. Emissions of pollutants are divided into organized and unorganized. Organized emissions are emissions diverted from the places of emission by a system of gas outlets, which makes it possible to use appropriate installations to capture them. Unorganized emissions are emissions that occur due to leaks in process equipment, gas outlets, tanks, open places of dusting and evaporation, etc. An inventory should be carried out for both organized and fugitive emissions. Sources of emission and release of pollutants at the asphalt plant are given in Table. 2.1. During the operation of the asphalt plant, the following pollutants are released into the atmosphere: inorganic dust, with different content of silicon dioxide; oxides of carbon and nitrogen; sulfurous anhydride (sulfur dioxide); hydrocarbons, in particular polycyclic ones: fuel oil ash (in terms of vanadium) when using fuel oil as a fuel; soot during the operation of transport on diesel fuel; lead and its inorganic compounds during the operation of vehicles on leaded gasoline. The classification of these emissions is given in Table. 2.2. In table. 2.3 shows the characteristics of emissions from sources of pollutant emission at the asphalt plant. Equipment that emits pollutants is equipped with dust and gas cleaning systems, which include: dust collectors of various types with gas ducts and smoke exhausters; devices that provide the required temperature conditions; hopper with mechanical means for supplying dust to the dispensers of the mineral powder unit. The equipment used for the deposition of dust from dusty gas can be divided into five main groups: dust collectors, cyclones, wet dust collectors, fabric filters and electrostatic precipitators. When storing tar, processing it into bitumen, heating bitumen and preparing asphalt concrete, hydrocarbons are released. The source of pollutant emissions at the asphalt plant are reactor plants for the preparation of bitumen from oil tar by oxidizing the latter with atmospheric oxygen. According to the principle of operation, reactor installations can be of a non-compressor type (T-309) - in them, atmospheric air is injected and sprayed into the oxidized raw material as a result of the rotation of the dispersers; or bubbling, in which air is supplied by a compressor (type SI-204). In reactor plants, during the oxidation of tar, 5-140 kg of oxidation gases are released per 1 ton of finished bitumen, depending on its brand, as well as on the quality of the feedstock. Oxidation gases contain about 5% hydrocarbons. The oxidation gases exit the reactor into a manifold connected to a hydrocyclone. Steam and the bulk of hydrocarbons condense in it, forming water and a "black solarium". Some of the hydrocarbons - about 20% of their initial amount - are fed together with other components of the oxidation gases into a special afterburner, which is part of the reactor plant complex. In the event that the reactor plant is not provided with an afterburner, the specific emission of a pollutant (hydrocarbons) can be taken as an average of 1 kg per 1 ton of finished bitumen.Table 2.1
Sources of emission and release of pollutants at the asphalt plant
Site name |
Name of emission sources |
Name of emission sources |
1. Asphalt mixing department | 1. Place for pouring stone materials into the unloading box 2. Unit for connecting the dryer drum to the unloading box 3. Drying drum 4. Elevator of the dryer drum 5. Screen 6. Places for pouring fillers into bunkers 7. Agitators 8. Pneumatic transport of filler into silos | Dust collectors with exhaust pipes | 2 Bitumen department | 1. Bitumen boilers (tar storage, bitumen storage) | exhaust pipes | 3. Stone crushing department | 1. The place of pouring the stone into the receiving hopper 2. jaw crusher 3. Cone crusher 4. Screen 5. Place for transfer of ground materials from the conveyor | Fugitive Emissions | 4. Department for the preparation of mineral powder | 1. Drying drum 2. Ball mill 3. Powder unloading unit (place of pouring) | Exhaust pipe of dryer drum | 5. Stacks of sand and gravel, loading and unloading platforms | Fugitive Emissions | 6. Soil mixing plant | 1. Agitator 2. Cement supply unit 3. Mineral materials hopper 4. Organic binder preparation and dosing unit | Fugitive Emissions | 7. Emulsion shop | 1. Organic binder preparation and heating unit 2. Emulsifier solution preparation unit | Luke Luke | 8. Boiler room | 1. Furnace device | Chimney |
Table 2.2
Classification of asphalt emissions into the atmosphere
No. p / p (code) |
Name (formula) of compounds |
Hazard Class |
Lead and its inorganic compounds (in terms of lead) | Nitrogen oxides (in terms of NO 2) | Soot | Sulfurous anhydride (sulfur dioxide - SO 2) | Carbon monoxide (CO) | Limit hydrocarbons C 12 - C 19 (in terms of total organic carbon) | Fuel oil ash (in terms of vanadium) | Inorganic dust (SiO 2 > 70%) Dinas and others. | Inorganic dust (SiO 2 = 20-70%) cement, fireclay, etc. | Inorganic dust (SiO 2<20 %) известняк и др. |
Characteristics of emission sources
List of pollutants emitted into the atmosphere |
Sources |
oil ash |
Lead and his |
allocation |
(inorganic) |
carbon |
hydrocarbons |
(in terms of vanadium) |
inorganic compounds |
Place of unloading and storage of mineral materials | Drying department | asphalt mixing plant | Reactor plant for the preparation of bitumen from tar | Bitumen melting plant | Tar storage (bitumen storage) | Boiler house chimney | crushing and screening plant | Emulsion shop | Shop for the preparation of reinforced soils | Automobile transport |
Table 3.4
Technical characteristics of emission sources
Options |
The Parameter Value of Asphalt Mixing Plants |
||||||||||||||
Type of asphalt mixing plants | DS-168 | DS-1683 | DS-185 (DS-1852, DS-1854, DS-1859) | D-597 (type) | D-597-A (D-508-2A) | D-617 | D-617-2 | D-645-2 | Teltomat 100 MA 5/3-5 | DS-158 | Drying drum CM-168 complete with ball mill OM-136 | ||||
Nominal productivity, t/h | |||||||||||||||
Characteristics of gas cleaning equipment (type, stage) | Preliminary stage - direct-flow axial cyclone with a diameter of 1256 mm | Stage I - direct-flow axial cyclone, diameter 1256 mm | I stage direct-flow axial cyclone with a diameter of 700 mm | Stage I - 4 cyclones TsN-15, 500 mm in diameter | Stage I - 4 cyclones SDK TsN-33, 800 mm in diameter | Stage I - 8 cyclones TsN-15, 650 mm in diameter | I stage - 12 cyclones TsN-15, 650 mm in diameter | Dust collecting unit E6 A-5-S, 4 cyclone batteries | Stage I - 8 cyclones TsN-15, 650 mm in diameter | Stage I - 2 cyclones TsN-15, 450 mm in diameter | |||||
I stage of cleaning - 10 cyclones STsN-40 with a diameter of 1000 mm | II stage - 10 cyclones STsN-40, 1000 mm in diameter | II stage - 4 cyclones STsN-40 with a diameter of 1000 mm | II stage - bubbling dust collector "Svetlana" | Stage II - cyclone washer SIOT | II stage - rotoclone | Stage II - cyclone - SIOT washer | P stage - rotoclone | II stage - rotoclone | P stage-scrubber "Venturi" | II stage - cyclone-washer SIOT | |||||
II stage of cleaning - wet dust collector of shock-inertial action type PVM | III stage - pipe "Venturi- | III stage - "Venturi" pipe | |||||||||||||
Overall average efficiency of the dust collection system, % | |||||||||||||||
Emission source characteristic: chimney height, m | |||||||||||||||
mouth diameter, m | |||||||||||||||
Parameters of the gas-air mixture at the outlet of the emission source: - velocity, m/s | |||||||||||||||
- volume, m 3 / s | |||||||||||||||
temperature, ° С | The concentration of dust entering the cleaning, g / m 3 (C) | ||||||||||||||
3. CALCULATION OF POLLUTANT EMISSIONS
3.1. Calculation of gross dust emissions
3.1.1. The gross emission of dust from the drying, mixing and grinding units is calculated by the formulaM p = 3600 × 10 -6 × t × V × С, t/year (3.1.1)
Where: t - operating time of technological equipment per year, h; V is the volume of exhaust gases, m 3 / s (Table 2.4); C is the concentration of dust supplied for cleaning, g / m 3 (Table 2.4). The maximum one-time release is calculated by the formula:
G = V × C, g/s (3.1.2)
The concentration of dust in the exhaust gases after their purification is calculated by the formula:
C 1 \u003d C (100 - h) × 10 -2, g / m 3 (3.1.3)
Where: h is the coefficient of purification of the dust-gas mixture, % (Table 2.4). 3.1.2. When transporting mineral material (sand, crushed stone) by a belt conveyor, dust emission from 1 m of the conveyor (maximum one-time emission) is calculated by the formula.
G T \u003d W s × l × g × 10 3, g / s (3.1.4)
Where: W s - specific blow off of dust (W s \u003d 3 × 10 -5 kg / (m 2 × s); l - conveyor belt width, m; g - rock mass grinding index (for belt conveyors g \u003d 0.1 m ) Gross dust emission is calculated by the formula:
M p = 3600 × 10 -6 × t 1 × G T, t/year (3.1.5)
Where: t 1 - operating time of the conveyor per year, hours 3.1.3. Dust emission during loading, unloading and storage of mineral material can be approximately calculated by the formula:
M c = b × P × Q × K 1 w × K zx × 10 -2, t/year (3.1.6)
Where: b - coefficient taking into account the loss of materials in the form of dust, fractions of a unit, b crushed stone = 0.03; b sand = 0.05; P - loss of material,% (assigned according to Table 3.1); Q - mass of building material, t/year; K 1 w - coefficient taking into account the moisture content of the material (assigned according to Table 3.2); K zx × - coefficient taking into account storage conditions (Table 3.3). The maximum one-time release is calculated by the formula:
G/s (3.1.7)
Where: n is the number of days of work of the asphalt plant in a year; t 2 - working time per day, h.
Table 3.1
Norms of natural attrition (losses) of road construction materials, % (P)
Material |
Type of storage and stacking |
In warehousing |
When loading |
When unloading |
Crushed stone, incl. black | Open warehouse in stacks | gravel, sand | With mechanized storage | Cement, mineral powder, lime | Closed warehouses: - silo type | lumpy | - bunker type and barn | cold asphalt | Outdoor warehouse (in stacks or under a canopy) | Bitumen, tar, emulsion, lubricants, etc. | Closed pits or tanks Side open pits |
Table 3.2.
Dependence of K 1 w on material moisture
Moisture content, % |
0-0,5 | over 0.5 to 1.0 | over 1.0 to 3.0 | over 3.0 to 5.0 | over 5.0 to 7.0 | over 7.0 to 8.0 | over 8.0 to 9.0 | over 9.0 up to 10 | over 10 |
Table 3.3.
Dependence of K 2x on local conditions
Local conditions |
Warehouses, open storages: | - from 4 sides | - from 3 sides | - from 2 sides | - from the 1st side | - loading sleeve | - closed on 4 sides |
3.2. Calculation of gross particulate emissions from fuel combustion
Gross emission of particulate matter (fuel oil ash) is calculated by the formula:t/year (3.2.1)
Where g T is the ash content of the fuel in% (fuel oil - 0.1%); m - amount of fuel consumed, t/year: c - dimensionless coefficient (fuel oil-0.01); h T - efficiency of ash collectors according to the passport data of the installation, %. The maximum one-time release is calculated by the formula:
G/s (3.2.2)
where: t 3 - equipment operation time per day, h.
3.3. Calculation of gross emissions of sulfurous anhydride (sulfur dioxide)
Gross emission of sulfur dioxide in terms of SO 2 is calculated by the formula:M so2 = 0.02BS p (1 - h ¢ so2) × (1 - h ¢ ¢ so2), × t / year (3.3.1)
Where: B - liquid fuel consumption, t / year; S p is the sulfur content in the fuel, % (Table 3.4); h ¢ so 2 - the proportion of sulfurous anhydride bound by fly ash fuel (when burning fuel oil h ¢ so 2 = 0.02); h ¢ ¢ so 2 - the proportion of sulfurous anhydride captured in the ash catcher. For dry ash collectors it is taken equal to zero. and for wet ones - according to the schedule (Fig. 3.1) depending on the alkalinity of the irrigation water and the reduced sulfur content of the fuel S p p p .
S p p p \u003d S P / Q p n,% kg / MJ (3.3.2)
Where Q p n is the calorific value of natural fuel, MJ / kg, m 3 (Table 3.4). The maximum one-time release is determined by the formula:
, g/s (3.3.3)
1 - 10 meq / dm 3;
2 - 5 meq / dm 3;
3 - 0 meq / dm 3;
S p p p is the reduced sulfur content of the fuel, (% kg) / MJ.
Rice. 3.1 The degree of capture of sulfur oxides in wet ash collectors h ¢ ¢ so2 at alkalinity of irrigation water
Table 3.4
Fuel characteristic
Type of fuel |
Q r n, Mj / kg, m 3 |
Fuel oil: | low sulfur | Sulfur | high sulfur | Natural gas from gas pipelines: Saratov-Moscow | Saratov-Gorky | Stavropol-Moscow | Serpukhov-Leningrad | Bryansk-Moscow | Promyslovka-Astrakhan | Stavropol-Nevinnomyssk-Grozny |
3.4. Calculation of gross emissions of nitrogen oxides
Gross emissions of nitrogen oxides (in terms of NO 2) emitted into the atmosphere are calculated using the formula:M NO 2 \u003d 0.001 × B × Q p n × K NO 2 × (1 - b), t / year (3.4.1)
where: B - fuel consumption, t / year. For gaseous fuel:
B = V × r , t/year (3.4.2)
Where: V - consumption of natural gas, thousand m 3 / year; r is the density of natural gas, kg / m 3 (r \u003d 0.76-0.85); K NO 2 × - a parameter characterizing the amount of nitrogen oxides generated per 1 GJ of heat, kg / GJ (Table 3.5); b - coefficient taking into account the degree of reduction of nitrogen oxide emissions as a result of the application of technical solutions. In the absence of technical solutions b = 0; Q p n × - heat of combustion of fuel, MJ / kg (Table 3.4).
Table 3.5
The value of the parameter K NO 2, kg / GJ
The maximum one-time release is calculated by the formula:, g/s (3.4.3)
3.5. Calculation of gross carbon monoxide emissions
Gross carbon monoxide emissions are calculated using the formula:, t/year (thousand m 3 /year) (3.5.1)
Where: C with o - the output of carbon monoxide during fuel combustion, kg / t of liquid fuel or kg / thousand. m 3 of natural gas, calculated by the formula:
C co \u003d g 3 × R × Q p n, kg / t or kg / thousand. m 3 , (3.5.2)
where: g 3 × - heat loss due to chemical incompleteness of fuel combustion,% (approximately for fuel oil and natural gas g 3 ×= 0.5%); R - coefficient taking into account the share of heat loss due to chemical incompleteness of fuel combustion, due to the presence of carbon monoxide in the products of incomplete combustion (for natural gas - R = 0.5, for fuel oil - R = 0.65); G 4 - heat loss due to mechanical incompleteness of fuel combustion,% (approximately for fuel oil and gas G 4 = 0%). The maximum one-time release is determined by the formula:
, g/s (3.5.3)
3.6. Calculation of gross emissions of fuel oil ash 1
__________ 1 - for boilers burning liquid fuel. Gross emissions of fuel oil ash in terms of vanadium, emitted into the atmosphere with flue gases of boilers, units. time is calculated by the formula:М v 205 = 10 -6 × C v × B × (1 - h os), t/year (3.6.1)
where: C v - the amount of vanadium contained in 1 ton of fuel oil, g/t;
g/t (3.6.2)
Where g T - ash content in fuel oil per working mass (fuel oil - 0.1%); B - fuel consumption for the period under review, t/year; h os - the proportion of vanadium deposited with solid particles on the heating surfaces of oil-fired boilers (in fractions of a unit); 0.07 - for boilers with industrial superheaters, the cleaning of the heating surface of which is carried out in a stopped state; 0.05 - for boilers without industrial superheaters under the same cleaning conditions; 0 - for other cases. The maximum one-time release is calculated by the formula:
, g/s (3.6.3)
3.7. Calculation of gross hydrocarbon emissions
Calculation of the gross release of hydrocarbons from storage tanks for road bitumen or oil tar due to evaporation is carried out based on the results of instrumental measurements of the maximum one-time release.3.8. Calculation of gross dust emissions from stone crushing and screening plants
The annual dust emission during the operation of a stone crushing and screening plant is calculated using formula 3.1.1. The indicators of dust emissions from stone crushing and screening plants are given in Table. 3.15.Table 3.15
Release sources |
The volume of polluted air, m 3 / h |
Dust concentration, g/m 3 (С) |
1. Crushing jaw crusher (900 ´1200 ´130); (1200 ´1500 ´150) | igneous rocks | carbonate rocks | Cone crusher (CODE 1200; CODE 1750) | igneous rocks | carbonate rocks | Impact crusher | igneous rocks | carbonate rocks | 2. Screening Screen GIL-52 | igneous rocks | carbonate rocks | 3. Transport Conveyor | igneous rocks | carbonate rocks |
3.9. Calculation of gross emissions of pollutants at reactor plants for the preparation of bitumen and in emulsion shops
During the operation of reactor plants, the following are emitted into the atmosphere: hydrocarbons, fuel oil ash (in terms of vanadium), oxides of sulfur, carbon and nitrogen, as well as solid particles. The calculation of gross emissions of these substances is carried out in accordance with paragraphs. 3.2 - 3.6 of this methodology. When bitumen emulsions are produced in emulsion shops, bitumen can be supplied to the disperser in a heated form through a pipeline from the ABZ bitumen melting plant, or it can be heated in boilers on the territory of the emulsion shop. In the first case, only gross hydrocarbon emissions are calculated in accordance with clause 3.7 of this methodology, in the second case, gross emissions of hydrocarbons, fuel oil ash (in terms of vanadium), sulfur oxides, carbon and nitrogen oxides, as well as particulate matter are calculated.3.10. Calculation of gross emissions of pollutants in shops for the preparation of reinforced soils
Reinforced soils in the workshops located on the territory of the asphalt plant are prepared on stationary or semi-stationary type plants (most often of the DS-50 type). Mixtures are prepared using mineral (cement, lime, fly ash), organic (bitumen, tar, tar) or complex binders (mineral and organic). During the operation of the installations, dust is emitted into the atmosphere (at the places of loading and dosing of mineral materials), as well as hydrocarbons (when organic or complex binders are used) in the area of preparation of organic binders. Most often, at these installations, organic binders are heated using electricity (electric heaters). To calculate dust emissions, the formulas given in paragraph 3.1 are used, and hydrocarbons in accordance with paragraph 3.7 of this methodology. When using fuel oil for heating organic binders, it is also necessary to take into account emissions of fuel oil ash (in terms of vanadium), sulfur oxides, carbon and nitrogen, as well as particulate matter (paragraphs 3.2 - 3.6).3.11. Calculation of emissions of pollutants from fuel combustion in boiler units of a boiler house
Boiler units of boiler houses operate on various types of fuel (solid, liquid and gaseous), so emissions of pollutants from their combustion will be different. The pollutants considered include: nitrogen dioxide, carbon monoxide, sulfur dioxide, particulate matter, and in the case of fuel oil combustion - fuel oil ash (in terms of vanadium). Calculation of emissions of the above pollutants from fuel combustion in own boiler houses is carried out in accordance with the current methodology. When calculating the maximum single emission, the fuel consumption for the coldest month of the year (t, thousand m 3) is taken.3.12. Calculation of emissions of pollutants from mobile sources
On the territory of the asphalt plant, mobile sources include vehicles that carry out intra-factory technological transportation. The calculation of gross and maximum one-time emissions from these vehicles is carried out in accordance with the current methodology, while the coefficient of release of cars on the line and the passing time is taken equal to 1. If there is a quarry at the asphalt plant, then the gross and maximum one-time emissions from cars are determined by the method.3.13. Calculation of gross emissions of pollutants in quarries
When developing quarries, it is necessary to take into account emissions of pollutants during excavation, loading and drilling operations. 3.13.1. Emissions during excavation and loading operations The maximum one-time amount of dust released into the atmosphere when loading by an excavator into dump trucks is calculated by the formula:, g/s (3.13.1)
Where P 1 - the content of silt and clay particles in the rock, in fractions of a unit. P 1 = 0.05; P 2 - coefficient taking into account the wind speed in the excavator operation area (Table 3.13.1 or submitted by the meteorological service); P * 3 - coefficient taking into account the moisture content of the material (Table 3.2, section 3.1); ___________ * For year-round operation of the quarry, take into account P z \u003d 0.01. P 4 - coefficient taking into account local conditions (Table 3.3, section 3.1) g - the amount of rock processed by the excavator, t / h.
Table 3.13.1
Wind speed, m/s |
up to 2 | up to 5 | to 10 | up to 20 | over 20 |
, t/year (3.13.2)
Where t 4 is the operating time of the excavator per year, hour. 3.13.2. Emissions of pollutants during drilling operations
, g/s (3.13.3)
Where N is the number of simultaneously operating drilling rigs; g is the amount of dust emitted during drilling with one machine, g/h; h is the efficiency of the dust cleaning system (Table 3.13.2), in fractions of a unit.
Table 3.13.2
Gross dust emission is calculated by the formula:, t/year (3.13.4)
Where G 6 - single emission of dust during drilling, g/s; t 5 - drilling time per day, hour; n 1 - the number of drilling days per year.
LITERATURE
1. Recommendations on the technology of heating tar with heat from the combustion of oxidation gases. Rostov-on-Don, 1983. 2. Guidelines for the calculation of emissions of pollutants into the atmosphere from asphalt concrete plants. Department of Scientific and Technical Information of the ACS, M., 1989. 3. GOST 17.2.4.05-83 Nature Protection. Atmosphere. Gravimetric method for the determination of suspended dust particles. 4. GOST 873693 Content of dust and clay particles in sand.5. Guidelines for the calculation of pollutant emissions from fuel combustion in boilers with a capacity of up to 30 t/h. M., Gidrometeoizdat, 1985. 6. Calculation of emissions of fuel oil ash from power plants and boiler houses (Appendix 2 to the letter of the Ministry of Natural Resources of Russia No. 27-2-15 / 73 dated 10.03.94. 7. Collection of methods for calculating emissions of pollutants into the atmosphere by various industries L., Gidrometeoizdat, 1986. 8. Methodology for conducting an inventory of emissions of pollutants into the atmosphere for motor transport enterprises (calculation method), M, 1998. 9. Methodology for calculating harmful emissions (discharges) and assessing environmental damage during the operation of various types of quarry transport. M., 1994.FEDERAL ROAD AGENCY
ORDER
ABOUT THE APPROVAL OF DOCUMENTATION FOR PLANNING
TERRITORIES OF THE OBJECT "CONSTRUCTION AND RECONSTRUCTION
SECTIONS OF THE ROAD M-51, M-53, M-55 "BAIKAL" -
FROM CHELYABINSK THROUGH KURGAN, OMSK, NOVOSIBIRSK, KEMEROVO,
KRASNOYARSK, IRKUTSK, ULAN-UDE TO CHITA. RECONSTRUCTION
ROAD R-258 "BAIKAL" IRKUTSK - ULAN-UDE -
CHITA ON THE SECTION KM 830+000 - KM 835+000,
ZABAYKALSKY KRAI"
In accordance with Article 45 of the Town Planning Code of the Russian Federation, Decree of the Government of the Russian Federation of July 26, 2017 N 884 "On approval of the Rules for the preparation of documentation for the planning of the territory, the preparation of which is carried out on the basis of decisions of authorized federal executive bodies, and the adoption by authorized federal executive bodies authorities of decisions on the approval of documentation on the planning of the territory for the placement of objects of federal importance and other capital construction objects, the placement of which is planned in the territories of 2 or more constituent entities of the Russian Federation", by order of the Ministry of Transport of Russia dated July 6, 2012 N 199 "On approval of the procedure for preparing documentation for planning of the territory intended for the placement of public roads of federal significance "and on the basis of the appeal of the FKU Uprdor "Transbaikalia" dated June 6, 2018 N 05/1687:
1. Approve the documentation for planning the territory of the facility "Construction and reconstruction of sections of the highway M-51, M-53, M-55" Baikal "- from Chelyabinsk through Kurgan, Omsk, Novosibirsk, Kemerovo, Krasnoyarsk, Irkutsk, Ulan-Ude to Chita Reconstruction of the R-258 "Baikal" highway Irkutsk - Ulan-Ude - Chita on the section km 830 + 000 - km 835 + 000, Trans-Baikal Territory, which is an annex to this order (not given).
2. The Department of Land and Property Relations (A.G. Lukashuk) notify FKU Uprdor "Zabaykal'e" of the decision taken, specified in paragraph 1 of this order.
3. FKU Uprdor "Transbaikalia":
within seven days from the date of approval of this order, ensure that the territory planning documentation certified by the seal of FKU Uprdor "Zabaikalye" is sent to the head of the rural settlement "Khilogosonskoye" of the Khiloksky district of the Transbaikal Territory for the execution of part 16 of article 45 of the Town Planning Code of the Russian Federation;
ensure that documents are sent to the registration authority for entering into the Unified State Register of Real Estate the information specified in paragraph 10 of the Rules for the provision of documents sent or provided in accordance with parts 1, 3 - 13, 15 of Article 32 of the Federal Law "On State Registration of Real Estate" to the federal executive authority (its territorial bodies) authorized by the Government of the Russian Federation to carry out state cadastral registration, state registration of rights, maintain the Unified State Register of Real Estate and provide information contained in the Unified State Register of Real Estate, approved by the Decree of the Government of the Russian Federation of December 31, 2015. N 1532.
MINISTRY OF TRANSPORT OF THE RUSSIAN FEDERATION
METHODOLOGY
INVENTORY OF POLLUTANT EMISSIONS
INTO THE ATMOSPHERE FOR MOTOR TRANSPORT ENTERPRISES
(BY CALCULATION METHOD)
The methodology for conducting an inventory of emissions of pollutants into the atmosphere for motor transport enterprises was developed by order of the Ministry of Transport of the Russian Federation.
The methodology is designed to calculate gross and maximum one-time emissions from mobile and stationary sources located on the territory of a motor transport enterprise.
With the release of this Methodology for conducting an inventory of emissions of pollutants into the atmosphere for motor transport enterprises, the previously existing Methodology with the same name, approved in 1992, and an addition to it, approved in 1993, are cancelled.
The following persons took part in the revision of the Method: Donchenko V.V., Manusadzhyants Zh.G., Samoilova L.G., Kunin Yu.I., Solntseva G.Ya. (NIIAT), Ruzsky A.V., Kuznetsov Yu.M. (MADI).
1. GENERAL PROVISIONS
This methodology establishes the procedure for calculating gross and maximum one-time emissions of pollutants from sources of air pollution on the territory of motor transport enterprises, regardless of their departmental affiliation and ownership, as well as freight stations and terminals, garages and car parks, organizations providing maintenance and repair services cars.
The main purpose of the inventory of pollutant emissions is to obtain initial data for:
development of draft standards for maximum permissible emissions of pollutants into the atmosphere both from enterprises as a whole and for individual sources of air pollution;
organization of control over compliance with established standards for emissions of pollutants into the atmosphere;
assessment of the environmental characteristics of technologies used at the enterprise;
planning of air protection works at the enterprise.
The calculation of gross and maximum single emissions of pollutants is carried out using specific indicators, i.e. the amount of emitted pollutants, reduced to the units of equipment used, the time of operation of vehicles or equipment, the mileage of vehicles, the mass of consumable materials.
Specific indicators of pollutant emissions from production sites are given on the basis of the results of studies and observations carried out by various research and design institutes
2. CALCULATION OF POLLUTANT EMISSIONS FROM CAR PARKING
In this methodology, a car park is understood as an area or room intended for storing cars for a certain period of time. Cars can be placed:
In separate open parking lots or in separate buildings and structures (closed parking lots) with direct entry and exit to public roads (calculation scheme 1, Fig. 1);
In open parking lots or in buildings and structures that do not have direct entry and exit to public roads and are located within the boundaries of the object for which the calculation is performed (calculation scheme 2, Fig. 1).
Gross and maximum one-time emissions of pollutants under the selected design scheme 1 are determined only for the parking area or premises, and under scheme 2 they are determined for each parking lot and for each internal passage.
The calculation of pollutant emissions from multi-storey parking lots is set out in the calculation scheme 3.
The calculation of pollutant emissions is carried out for six pollutants: carbon monoxide - CO, hydrocarbons - CH, nitrogen oxides -NO x, in terms of nitrogen dioxide NO 2, particulate matter - C, sulfur compounds, in terms of sulfur dioxide SO 2 and compounds lead - Pb. For vehicles with gasoline engines, emissions of CO, CH, NO x ,SO 2 and Pb are calculated (Pb - only for regions where leaded gasoline is used); with gas engines - CO, CH, NO x, SO 2; with diesel engines - CO, CH, NO x, C, SO 2.
Calculation scheme 1.
Emissions of the i-th substance by one car of the k-th group per day when leaving the territory or parking space and returning are calculated by the formulas:
where is the specific emission of the i-th substance when the engine of the car of the k-th group is warmed up, g/min;
Running emission of the i-th substance, by the car of the k-th group when driving at a speed of 10-20 km/h, g/km;
Specific emission of the i-th substance when the engine of the car of the k-th group is idling, g/min;
t np - engine warm-up time, min;
L 1 , L 2 - car mileage in the parking area, km:
Engine idling time when leaving the parking area and returning to it (min).
The values of specific emissions of pollutants ,, and for various types of vehicles are presented in Table. 2.1 2.18.
The following designations are used in the tables:
engine type: B - gasoline, D - diesel, G 1) - gas (compressed natural gas); when using liquefied petroleum gas, specific emissions of pollutants are equal to emissions when using gasoline, there is no Pb emission;
period of the year: T - warm, X - cold;
storage conditions
cars: BP - open or closed unheated parking lot without heating means; SP - open parking, equipped with heating facilities. For warm closed parking lots, specific emissions of pollutants in the cold and transitional periods of the year are taken equal to specific emissions in the warm period.
1) When engines operating on the gas-diesel cycle are used in motor vehicles, specific emissions are assumed to be equal to emissions when operating on diesel fuel.
When catalytic converters are installed on vehicles, the specific emission data given in tables 2.4 - 2.6, 2.14 - 2.15 are subject to reduction factors indicated in the notes to the tables.
The introduction of reduction factors for specific emissions, presented in tables 2.1 - 2.3, 2.7 - 2.13 and 2.16 - 2.18, when using catalytic converters, as well as in tables 2.1 - 2.18, when using any other devices designed to reduce pollutant emissions, can be carried out only in agreement with the regional bodies of the State Committee for Ecology. At the same time, an obligatory condition is the availability of an official conclusion of an independent examination confirming the effectiveness of the use of these devices on the corresponding car models in conditions typical for traffic on the territory of parking lots.
Calculation scheme 1.
Calculation scheme 2.
Rice. 1. Options for parking lots
1 - parking area or premises;
2 - public roads;
3 - entry from a public road;
4 - exit to public roads;
5 - internal driveways;
6 - buildings and structures not intended for parking.
Table 2.1.
Specific emissions of pollutants during warming up of passenger car engines
Russian Federation Order of the Ministry of Transport of Russia
Methodology for conducting an inventory of emissions of pollutants into the atmosphere for asphalt concrete plants (calculation method)
set a bookmark
set a bookmark
METHODOLOGY
inventory of pollutant emissions
into the atmosphere for asphalt concrete plants (calculation method)
AGREED by the State Committee of the Russian Federation for Environmental Protection and Hydrometeorology on August 26, 1998 N 05-12 / 16-389
APPROVED by the Ministry of Transport of the Russian Federation on October 28, 1998
The preparation of the 2nd revised and supplemented edition of this Methodology was attended by: Ph.D. Donchenko V.V., Ph.D. Manusadzhyants Zh.G., Samoilova L.G., Solntseva G.Ya. (NIIAT), Ph.D. n. Mazepova V.I., Bobkov V.V., Berezhnaya Yu.A. (NPO RosdorNII).
INTRODUCTION
This methodology was developed by order of the Ministry of Transport of the Russian Federation and is designed to provide methodological assistance to employees of operating asphalt concrete plants (APP) in conducting an inventory of pollutant emissions, developing draft standards for maximum allowable emissions (MPE), environmental passports, determining the level of impact of individual emission sources on the air environment, predicting the magnitude of emissions for the future.
1. GENERAL PROVISIONS
The methodology establishes the procedure for calculating emissions of pollutants from technological equipment installed on the territory of the asphalt plant. As a rule, in addition to the main technological equipment for the preparation of asphalt concrete and the preparation of mineral and binder materials, there are numerous sites on the territory of the asphalt plant, the products of which are used in construction and repair work in the road industry.
The main purpose of the inventory of pollutants is to obtain initial data for:
- assessing the degree of impact of emissions of pollutants emitted by the asphalt plant on the environment (atmospheric air);
- development of draft standards for emissions of pollutants into the atmosphere, both from the asphalt plant as a whole and for individual sources of air pollution;
- organization of control over compliance with established standards for emissions of pollutants into the atmosphere;
- assessment of the environmental performance of technologies used at the asphalt plant;
- planning of air protection works at the asphalt plant.
The calculation of gross and maximum single emissions of pollutants is carried out using specific indicators, i.e. the amount of emitted pollutants, reduced to units of time, equipment, mass of consumable materials.
Specific indicators of pollutant emissions from production sites are given on the basis of the results of studies and observations carried out by various research and design institutes.
The work on the calculation of pollutant emissions is carried out by the ABZ either on its own, or for this purpose it attracts a specialized organization that has a license to carry out such work. If calculations of pollutant emissions are carried out by a specialized organization, then it must require the asphalt plant to provide data on the actual quantity and type of equipment, the quantity and grades of materials used, the number of days of operation per year for each piece of equipment and its net operating time per day. ABS is responsible for the completeness and reliability of the inventory data.
Calculation of emissions from asphalt plants should be carried out on the basis of the actual technical characteristics of this mixer. For reference, the Methodology provides technical characteristics for asphalt concrete plants that were produced earlier and make up the main fleet in road organizations.
2. SOURCES OF POLLUTANT EMISSIONS AT ASPHALT CONCRETE PLANTS
The industrial site of the asphalt plant, as a rule, includes workshops for the preparation of organic binder and asphalt concrete, the preparation of mineral materials, and boiler houses. Often, shops for the preparation of road viscous bitumen from raw materials (tar), bitumen emulsions, reinforced soils, stone crushing and screening plants are also located here.
ABZ can be equipped with sets of equipment of the following types: D-597, D-597A, D-508-2A, D-617, D-645-2, DS-117-2K (2E), DS-1895, D-158, "Teltomat" manufactured by Germany and other imported asphalt mixing plants with a capacity of 25, 32-42, 50, 100 and 200 t/h.
Sources of air pollution are divided into sources of emission and sources of emissions of pollutants into the atmosphere.
Sources of pollutant emission are: technological unit, installation, device, apparatus, etc., emitting pollutants during operation.
Sources of pollutant emissions are: a pipe, an aeration lamp, a bunker, a ventilation shaft, a manhole, etc. devices that release pollutants into the atmosphere.
Emissions of pollutants are divided into organized and unorganized.
Organized emissions are emissions diverted from the places of emission by a system of gas outlets, which makes it possible to use appropriate installations to capture them.
Unorganized emissions are emissions that occur due to leaks in process equipment, gas outlets, tanks, open places of dusting and evaporation, etc.
An inventory should be carried out for both organized and fugitive emissions.
The sources of emission and release of pollutants at the asphalt plant are given in Table 2.1.
Table 2.1
Sources of emission and release of pollutants at the asphalt plant
Site name | Name of emission sources | Name of emission sources |
1. Asphalt mixing department | 1. Place of pouring stone materials into the unloading box 2. Knot for connecting the dryer drum to the unloading box 3. Tumble dryer 4. Dryer elevator 6. Places for pouring fillers into bunkers 7. Agitators 8. Pneumatic transport of filler to silos | Dust collectors with exhaust pipes |
2. Bituminous department | 1. Bitumen boilers (tar storage, bitumen storage) | exhaust pipes |
3. Stone crushing department | 1. The place of pouring the stone into the receiving hopper 2. jaw crusher 3. Cone crusher 5. Place for pouring ground materials from the conveyor | Fugitive Emissions |
4. Department for the preparation of mineral powder | 1. Tumble dryer 2. Ball mill 3. Unloading unit (place of pouring) of powder | Dryer exhaust pipe Dust collectors |
5. Stacks of sand and gravel, loading and unloading platforms | Fugitive Emissions |
|
6. Soil mixing plant | 1. Stirrer 2. Cement supply unit 3. Bunker of mineral materials 4. Node for preparation and dosing of organic binder | Fugitive Emissions |
7. Emulsion shop | 1. Unit for preparation and heating of organic binder | |
2. Emulsifier solution preparation unit | ||
8. Boiler room | 1. Furnace device | Chimney |
During the operation of the asphalt plant, the following pollutants are released into the atmosphere: inorganic dust, with different content of silicon dioxide; oxides of carbon and nitrogen; sulfurous anhydride (sulfur dioxide); hydrocarbons, in particular polycyclic ones; when using fuel oil as a fuel; soot during the operation of transport on diesel fuel; lead and its inorganic compounds during the operation of vehicles on leaded gasoline.
The classification of these emissions is given in Table 2.2.
Table 2.2
Classification of asphalt emissions into the atmosphere
NN p/n (code) | Name (formula) of compounds | MPC m.s. | Hazard Class |
Lead and its inorganic compounds (in terms of lead) | |||
Nitrogen oxides (in terms of NO) | |||
Sulfur dioxide (sulfur dioxide - SO) | |||
Carbon monoxide (CO) | |||
Limit hydrocarbons C-C (in terms of total organic carbon) | |||
Fuel oil ash (in terms of vanadium) | |||
Dust inorganic (SiO70%) Dinas and others. | |||
Inorganic dust (SiO=20-70%) cement, fireclay, etc. | |||
Inorganic dust (SiO20%) limestone, etc. |
Table 2.3 shows the characteristics of emissions from sources of pollutant emissions at the asphalt plant.
Table 2.3
Characteristics of emission sources
Sources of selection | List of pollutants emitted into the atmosphere |
||||||||
Dust (inorganic | Carbohydrate | Fuel oil ash (in terms of vanadium) | Lead and its inorganic |
||||||
carbon | |||||||||
Place of unloading and storage of mineral materials | |||||||||
Drying department | |||||||||
asphalt mixing plant | |||||||||
Reactor plant for the preparation of bitumen from tar | |||||||||
Bitumen melting plant | |||||||||
Tar storage (bitumen storage) | |||||||||
Boiler house chimney | |||||||||
crushing and screening plant | |||||||||
Emulsion shop | |||||||||
Shop for the preparation of reinforced soils | |||||||||
Automobile transport |
Equipment that emits pollutants is equipped with dust and gas cleaning systems, which include: dust collectors of various types with gas ducts and smoke exhausters; devices that provide the required temperature conditions; hopper with mechanical means for supplying dust to the dispensers of the mineral powder unit. The equipment used for the deposition of dust from dusty gas can be divided into five main groups: dust collectors, cyclones, wet dust collectors, fabric filters and electrostatic precipitators.
When storing tar, processing it into bitumen, heating bitumen and preparing asphalt concrete, hydrocarbons are released.
The source of pollutant emissions at the asphalt plant are reactor plants for the preparation of bitumen from oil tar by oxidizing the latter with atmospheric oxygen.
According to the principle of operation, reactor installations can be of a non-compressor type (T-309) - in them, atmospheric air is injected and sprayed into the oxidized raw material as a result of the rotation of the dispersers; or bubbling, in which air is supplied by a compressor (type SI-204).
In reactor plants, during the oxidation of tar, 5-140 kg of oxidation gases are released per 1 ton of finished bitumen, depending on its brand, as well as on the quality of the feedstock. Oxidation gases contain about 5% hydrocarbons.
The oxidation gases exit the reactor into a manifold connected to a hydrocyclone. Steam and the bulk of hydrocarbons condense in it, forming water and a "black solarium".
Some of the hydrocarbons - about 20% of their initial amount - are supplied, together with other components of the oxidation gases, to a special afterburner, which is part of the reactor plant complex.
In the event that the reactor plant is not provided with an afterburner, the specific emission of a pollutant (hydrocarbons) can be taken as an average of 1 kg per 1 ton of finished bitumen.
Table 2.4
Technical characteristics of dust collection systems
Options | The Parameter Value of Asphalt Mixing Plants |
||||||||||||
Type of asphalt | DS-185 | D-597 (type) | D-597-A | DS-117-2K | Telto- | Sushil- |
|||||||
Produc- | 32-42 | ||||||||||||
Characteristics | Pre- | Stage I - direct | Stage I - direct | Stage I - 4 cyclones TsN-15, diameter | | Stage I - 4 cyclones SDK TsN-33, diamet- | | Stage I - 8 cyclones TsN-15, diameter | Stage I - 12 cyclones TsN-15, diameter | dusty- | Stage I - 8 cyclones TsN-15, diameter | Stage I - 2 cyclones TsN-15, diameter |
|
I stage of cleaning - 10 cyclones STsN-40 diamet- | Stage II - 10 cyclones STsN-40, diameter | Stage II - 4 cyclones STsN-40 diamet- | II stage - barbot- | II stage - cyclone - industrial | II stage - rotoclone | Stage II - cyclone - washing - | II - stage - rotoclone | II stage - rotoclone | II - stage-scrubber "Venturi" | Stage II - cyclone - washing - |
|||
II stage of cleaning - wet dust collector | III stage - "Venturi" pipe | III stage - "Venturi" pipe | |||||||||||
The overall average efficiency of the dust collector system is | |||||||||||||
Character- | |||||||||||||
chimney height, m | |||||||||||||
mouth diameter, m | |||||||||||||
Gas air parameters | |||||||||||||
Speed, m/s | |||||||||||||
Volume, m/s | |||||||||||||
tempera- | |||||||||||||
Concentration- |
3. CALCULATION OF POLLUTANT EMISSIONS
3.1. Calculation of gross dust emissions
3.1.1. The gross emission of dust from the drying, mixing and grinding units is calculated by the formula:
T/year (3.1.1)
Where: - operating time of technological equipment per year, h;
The volume of exhaust gases, m / s (Table 2.4);
The concentration of dust entering the cleaning, g / m (Table 2.4).
G/s, (3.1.2)
The concentration of dust in the exhaust gases after their purification is calculated by the formula:
Where: - coefficient of purification of the dust-gas mixture, % (Table 2.4).
3.1.2. When transporting mineral material (sand, crushed stone) by a belt conveyor, dust emission from 1 m of the conveyor (maximum one-time emission) is calculated by the formula:
G/s, (3.1.4)
where: - specific blow off of dust (3 10 kg/(m s);
Conveyor belt width, m;
The index of grinding the rock mass (for belt conveyors 0.1 m).
T/year (3.1.5)
Where: - operating time of the conveyor per year, h.
3.1.3. Dust emission during loading, unloading and storage of mineral material can be approximately calculated by the formula:
T/year (3.1.6)
Where: - coefficient taking into account the loss of materials in the form of dust, fractions of a unit, 0.03; 0.05;
Loss of material, % (assigned according to Table 3.1);
Mass of building material, t/year;
Coefficient taking into account the moisture content of the material (assigned according to Table 3.2);
Coefficient taking into account storage conditions (Table 3.3).
The maximum one-time release is calculated by the formula:
Where: - the number of days of work of the asphalt plant in a year;
Working hours per day, hours
Table 3.1
Norms of natural attrition (losses) of road construction materials, % (P)
Material | Type of storage and installation | In warehousing | When loading | When unloading |
Crushed stone, incl. black gravel, sand | Open warehouse in stacks | |||
With mechanized storage | ||||
Cement, mineral powder, lump lime | Closed warehouses: Silo type | |||
Bunker type and barn | ||||
cold asphalt | Outdoor warehouse (in stacks or under a canopy) | |||
Bitumen, tar, emulsion, lubricants, etc. | Closed pit storages or tanks | |||
Vaults open on the sides |
Table 3.2
Dependence on material moisture
Moisture content, % | |
over 0.5 to 1.0 | |
over 1.0 to 3.0 | |
over 3.0 to 5.0 | |
over 5.0 to 7.0 | |
over 7.0 to 8.0 | |
over 8.0 to 9.0 | |
over 9.0 up to 10 | |
Table 3.3
Dependence on local conditions
3.1.4. The total gross dust emission is determined by summing the gross emissions from all dust sources at the asphalt plant.
3.2. Calculation of gross particulate emissions from fuel combustion
Gross emission of particulate matter (fuel oil ash) is calculated by the formula:
T/year (3.2.1)
Where is the ash content of the fuel in% (fuel oil - 0.1%);
The amount of fuel consumed, t/year;
Dimensionless coefficient (fuel oil - 0.01);
Efficiency of ash collectors according to the passport data of the installation, %.
The maximum one-time release is calculated by the formula:
Where: - equipment operation time per day, h.
3.3. Calculation of gross emissions of sulfurous anhydride (sulfur dioxide)
Gross emission of sulfur dioxide in terms of SO is calculated by the formula:
T/year (3.3.1)
Where: - liquid fuel consumption, t/year;
Sulfur content in fuel, % (Table 3.4);
The share of sulfurous anhydride bound by fly ash of fuel (when fuel oil is burned 0.02);
Percentage of sulfurous anhydride captured in the ash catcher. For dry ash collectors, it is taken equal to zero, and for wet ones - according to the schedule (Fig. 3.1) depending on the alkalinity of the irrigating water and the reduced sulfur content of the fuel.
, % kg/MJ (3.3.2)
Where is the heat of combustion of natural fuel, MJ / kg, m (Table 3.4).
G/s (3.3.3)
1 - 10 meq/dm;
2 - 5 meq/dm;
3 - 0 meq/dm;
Reduced fuel sulfur content, (% kg)/MJ.
Fig. 3.1 Degree of sulfur oxides capture in wet ash collectors with alkalinity of irrigation water *
__________________
* The drawing corresponds to the original. - Note "CODE".
Table 3.4
Fuel characteristic
Type of fuel | MJ/kg, m |
|
low sulfur | ||
Sulfur | ||
high sulfur | ||
Natural gas from gas pipelines: | ||
Saratov-Moscow | ||
Saratov-Gorky | ||
Stavropol-Moscow | ||
Serpukhov-Leningrad | ||
Bryansk-Moscow | ||
Promyslovka-Astrakhan | ||
Stavropol-Nevinnomyssk-Grozny |
3.4. Calculation of gross emissions of nitrogen oxides
Gross emissions of nitrogen oxides (in terms of NO) emitted into the atmosphere are calculated using the formula:
T/year (3.4.1)
Where: - fuel consumption, t/year.
For gaseous fuel:
T/year (3.4.2)
Where: - consumption of natural gas, thousand m / year;
Density of natural gas, kg/m (0.76-0.85);
Parameter characterizing the amount of nitrogen oxides generated per 1 GJ of heat, kg/GJ (Table 3.5);
Coefficient that takes into account the degree of reduction in nitrogen oxide emissions as a result of the application of technical solutions.
In the absence of technical solutions 0;
Fuel combustion heat, MJ/kg (Table 3.4).
Table 3.5
Parameter value, kg/GJ
The maximum one-time release is calculated by the formula:
3.5. Calculation of gross carbon monoxide emissions
Gross carbon monoxide emissions are calculated using the formula:
T/year (thousand m/year) (3.5.1)
Where: - carbon monoxide output during fuel combustion, kg/t of liquid fuel or kg/thous. m of natural gas is calculated by the formula:
kg/t or kg/thousand m, (3.5.2)
Where: - heat loss due to chemical incompleteness of fuel combustion, % (approximately for fuel oil and natural gas 0.5%);
Coefficient taking into account the proportion of heat loss due to chemical incompleteness of fuel combustion, due to the presence of carbon monoxide in the products of incomplete combustion (for natural gas -0.5, for fuel oil -0.65);
Heat loss due to mechanical incompleteness of fuel combustion, % (approximately for fuel oil and gas 0%).
The maximum one-time release is determined by the formula:
3.6. Calculation of gross emissions of fuel oil ash
For boilers burning liquid fuels.
Gross emissions of fuel oil ash in terms of vanadium, emitted into the atmosphere with flue gases of boilers, units. time is calculated by the formula:
T/year (3.6.1)
Where: - the amount of vanadium in 1 ton of fuel oil, g/t;
Where - the ash content in fuel oil per working mass (fuel oil - 0.1%);
Fuel consumption for the period under review, t/year;
The proportion of vanadium deposited with solid particles on the heating surfaces of oil-fired boilers (in fractions of a unit):
0.07 - for boilers with industrial superheaters, the cleaning of the heating surface of which is carried out in a stopped state;
0.05 - for boilers without industrial superheaters under the same cleaning conditions;
0 - for other cases.
The maximum one-time release is calculated by the formula:
3.7. Calculation of gross hydrocarbon emissions
Calculation of the gross release of hydrocarbons from storage tanks for road bitumen or oil tar due to evaporation is carried out based on the results of instrumental measurements of the maximum one-time release.
3.8. Calculation of gross dust emissions from stone crushing and screening plants
The annual dust emission during the operation of a stone crushing and screening plant is calculated using formula 3.1.1.
Indicators of dust emissions from stone crushing and screening plants are given in Table 3.15.
Table 3.15
Release sources | Volume of polluted air, m/h | Dust concentration, g/m (C) |
1. Crushing | ||
Jaw crusher (900x1200x130); (1200x1500x150) | ||
igneous rocks | ||
carbonate rocks | ||
Cone crusher (CODE 1200; CODE 1750) | ||
igneous rocks | ||
carbonate rocks | ||
Impact crusher | ||
igneous rocks | ||
carbonate rocks | ||
2. Screening | ||
Roar GIL-52 | ||
igneous rocks | ||
carbonate rocks | ||
3. Transportation | ||
Conveyor | ||
igneous rocks | ||
carbonate rocks |
3.9. Calculation of gross emissions of pollutants at reactor plants for the preparation of bitumen and in emulsion shops
During the operation of reactor plants, the following are emitted into the atmosphere: hydrocarbons, fuel oil ash (in terms of vanadium), oxides of sulfur, carbon and nitrogen, as well as solid particles. The calculation of gross emissions of these substances is carried out in accordance with paragraphs 3.2-3.6 of this methodology.
When bitumen emulsions are produced in emulsion shops, bitumen can be supplied to the disperser in a heated form through a pipeline from the ABZ bitumen melting plant, or it can be heated in boilers on the territory of the emulsion shop. In the first case, only gross hydrocarbon emissions are calculated in accordance with clause 3.7 of this methodology, in the second case, gross emissions of hydrocarbons, fuel oil ash (in terms of vanadium), sulfur oxides, carbon and nitrogen oxides, as well as particulate matter are calculated.
3.10. Calculation of gross emissions of pollutants in shops for the preparation of reinforced soils
Reinforced soils in the workshops located on the territory of the asphalt plant are prepared on stationary or semi-stationary type plants (most often of the DS-50 type). Mixtures are prepared using mineral (cement, lime, fly ash), organic (bitumen, tar, tar) or complex binders (mineral and organic).
During the operation of the installations, dust is emitted into the atmosphere (at the places of loading and dosing of mineral materials), as well as hydrocarbons (when organic or complex binders are used) in the area of preparation of organic binders. Most often, at these installations, the heating of organic binders is carried out using electricity (electric heaters).
To calculate dust emissions, the formulas given in clause 3.1 are used, and hydrocarbon emissions are used in accordance with clause 3.7 of this methodology. When using fuel oil for heating organic binders, it is also necessary to take into account emissions of fuel oil ash (in terms of vanadium), sulfur oxides, carbon and nitrogen, as well as particulate matter (clauses 3.2-3.6).
3.11. Calculation of emissions of pollutants from fuel combustion in boiler units of a boiler house
Boiler units of boiler houses operate on various types of fuel (solid, liquid and gaseous), so emissions of pollutants from their combustion will be different.
The pollutants considered include: nitrogen dioxide, carbon monoxide, sulfur dioxide, particulate matter, and in the case of fuel oil combustion - fuel oil ash (in terms of vanadium).
Calculation of emissions of the above pollutants from fuel combustion in own boiler houses is carried out in accordance with the current methodology.
When calculating the maximum single emission, the fuel consumption for the coldest month of the year (t, thousand m) is taken.
3.12. Calculation of emissions of pollutants from mobile sources
On the territory of the asphalt plant, mobile sources include vehicles that carry out intra-factory technological transportation.
The calculation of gross and maximum one-time emissions from these vehicles is carried out in accordance with the current methodology, while the coefficient of release of vehicles per line and the time of passing is taken equal to 1.
If there is a quarry at the asphalt plant, then the gross and maximum one-time emissions from cars are determined by the method.
3.13. Calculation of gross emissions of pollutants in quarries
When developing quarries, it is necessary to take into account the emissions of pollutants during excavation, loading and drilling operations.
3.13.1. Emissions during excavation and loading operations
The maximum one-time amount of dust released into the atmosphere when loading by an excavator into dump trucks is calculated by the formula:
G/s (3.13.1)
where - the content of silt and clay particles in the rock, in fractions of a unit, 0.05;
Coefficient taking into account the wind speed in the area of the excavator (Table 3.13.1 or according to the weather service);
* - coefficient taking into account the moisture content of the material (Table 3.2, Section 3.1);
________________
* For year-round work, the quarry is calculated to take 0.01.
Coefficient taking into account local conditions (Table 3.3, Section 3.1),
The amount of rock processed by the excavator, t / h.
Table 3.13.1
Wind speed, m/s | |
Gross dust emission is calculated by the formula:
T/year, (3.13.2)
Where is the operating time of the excavator per year, hour.
3.13.2. Emissions of pollutants from drilling operations
The maximum one-time dust emission during drilling of wells and shurps is calculated by the formula:
G/s, (3.13.3)
where is the number of simultaneously operating drilling rigs;
The amount of dust emitted during drilling with one machine, g/h;
The efficiency of the dust cleaning system (Table 3.13.2), in fractions of a unit.
Table 3.13.2
Gross dust emission is calculated by the formula:
T/year (3.13.4)
where is a one-time dust emission during drilling, g/s;
Drilling time per day, hour;
Number of drilling days per year.
7. Collection of methods for calculating emissions of pollutants into the atmosphere by various industries. L., Gidrometeoizdat, 1986.
9. Methodology for calculating harmful emissions (discharges) and assessing environmental damage during the operation of various types of open-pit transport. M., 1994.
The text of the document is verified by:
/ Ministry of Transport of the Russian Federation. -
M., 1998
conducting an inventory of emissions of pollutants into the atmosphere
at railway transport enterprises
(by calculation method)
TEAM OF AUTHOR: Donchenko V.V., Manusadzhyants Zh.G., Samoilova L.G. (NIIAT), Pekarsky I.V., Valyaev B.V. (Giprotransput), Pankov Yu.H. (MPS)
AGREED by the Deputy Minister of Ecology and Natural Resources of the Russian Federation N.G. Rybalsky on April 8, 1992; Head of the Atmosphere Control Department of the All-Russian Research Institute for Nature Conservation V.B. Milyaev December 15, 1991
APPROVED by the Deputy Minister of Transport of the Russian Federation VF Berezin on September 15, 1992; Head of the Scientific and Technical Department of the Ministry of Transport of the Russian Federation V.I. Tarasov September 14, 1992
1. Basic provisions
2. Calculation of pollutant emissions from fuel combustion in the boiler units of the boiler house
2.1. General provisions
2.2. Calculation of pollutant emissions from fuel combustion in boiler units of a boiler house
3. Enterprises for the processing of crushed stone
3.1. Production characteristic. Sources of emission and emissions of pollutants into the air
3.2. Definition of emissions from organized sources
3.3. Definition of emissions from fugitive sources
4. Rail welding enterprise
4.1. Production characteristic. Sources of emission and emissions of pollutants into the air
4.2. Cleaning joints before welding
4.3. Rail joint welding
4.4. Grinding welding joints
4.5. Surfacing of the tread surface of crosspieces of turnouts
5. Repair enterprises: car repair, diesel locomotive repair and mechanical plants
5.1. Production characteristic. Sources of emission and emissions of pollutants into the air
5.2. Assembly and disassembly areas
5.3. Areas for mechanical processing of metals and plastics
5.4. Areas for mechanical processing of wood
5.5. Sections of chemical and electrochemical processing of metals (galvanizing sections)
5.6. Metal welding and cutting areas
5.7. Areas for applying paint and varnish coatings
5.8. Thermal and forge-and-press sections
5.9. Sites for the manufacture of plastic and rubber products
5.10. Foundries
5.11. Battery section
5.12. Mednice branch
5.13. Engine break-in area after repair
6. Sleeper impregnation enterprises
6.1. Production characteristic. Sources of emission and emissions of pollutants into the air
6.2. Definition of outliers
7. Carriage and locomotive depots. Places of sludge and processing of wagons
7.1. Wagon and locomotive depots
7.2. Drying sand in a kiln
7.3. Places of sludge and processing of wagons
8. Guidelines for the calculation of pollutants emitted into the air by railway vehicles
8.1 General
8.2. Methods for calculating emissions of pollutants into the atmosphere with exhaust gases of railway vehicles
8.2.1. Determination of emissions from mainline diesel locomotives
Fig.8.1. Changes in the values of specific CO emissions by diesel freight locomotives depending on the weights of the transported trains
Fig.8.2. Changes in the values of specific emissions of NO(x) by diesel freight locomotives depending on the weight of the transported trains
Fig.8.3. Changes in the values of specific soot emissions by freight diesel locomotives depending on the weights of the transported trains
8.2.2. Determination of emissions from shunting diesel locomotives
8.2.3 Determination of emissions from industrial railway locomotives
8.2.4. Determination of emissions from refrigerated rolling stock
8.2.5. Determination of emissions from track railway equipment
9. Literature
1. Basic provisions
The Guidelines establish the procedure for calculating emissions of pollutants from stationary sources of existing and planned railway transport enterprises and can be used in the development of project documentation for the protection of the air from pollution in cases where the use of field measurements is difficult or impractical.
The calculation of emissions is based on the use of specific indicators, i.e. emissions of pollutants, reduced to a unit of time, equipment, mass of products received or consumed fuel, raw materials and materials.
Specific indicators of pollutant emissions from production equipment were identified based on the results of research conducted by research and design organizations at railway transport enterprises, as well as on the basis of available data obtained from similar industries in other sectors of the national economy.
These guidelines may subsequently be supplemented in connection with the emergence of new technological equipment, the use of other types of raw materials, materials and technological processes, data on which are currently not available.
2. Calculation of pollutant emissions from fuel combustion
in the boiler units of the boiler house
2.1. General provisions
The proposed calculation is designed to determine the emission of pollutants into the atmosphere with gaseous combustion products during the combustion of solid fuels, fuel oil and gas in the furnaces of industrial and municipal boilers and heat generators (small heating boilers, heating and welding machines, furnaces) with a capacity of up to 30 t/h.
When burning solid fuels, along with the main combustion products (CO, HO, NO), the following enter the atmosphere: fly ash with particles of unburned fuel, oxides, sulfur, carbon and nitrogen. When burning fuel oil with flue gases, sulfur oxides, nitrogen dioxide, solid products of incomplete combustion and vanadium compounds are emitted. When burning gas with flue gases, the following are emitted: nitrogen dioxide, carbon monoxide.
When compiling this section, the following were used: "Guidelines for the calculation of pollutant emissions from fuel combustion in boiler houses with a capacity of up to 30 t/h". Moscow, Gidrometizdat, 1985
2.2. Calculation of pollutant emissions from fuel combustion
in the boiler units of the boiler house
Boiler units of boiler houses operate on various types of fuel (solid, liquid and gaseous). Emissions of pollutants depend both on the amount and type of fuel, and on the type of boiler.
The considered pollutants emitted during fuel combustion are: particulate matter, carbon monoxide, nitrogen oxides, sulfur dioxide (sulphur dioxide), vanadium pentoxide.
1. Gross emission of solid particles in flue gases of boiler houses is determined by the formula: , t/year (2.2.1)
where: - ash content of the fuel, in% (Table 2.2.1);
- the amount of fuel consumed per year, t;
- dimensionless coefficient (Table 2.2.4);
- efficiency of ash collectors, % (Table 2.2.2.).
Table 2.2.1
Characteristics of fuels (under normal conditions)
#G0Name of fuel | , % | , % | , MJ/kg |
1 | 2 | 3 | 4 |
coals | |||
Donetsk basin | 28,0 | 3,5 | 13,50 |
Dnieper basin | 31,0 | 4,4 | 6,45 |
Moscow region basin | 39,0 | 4,2 | 9, 88 |
Pechora basin | 31,0 | 3,2 | 17,54 |
Kizelovsky basin | 31,0 | 6,1 | 19,65 |
Chelyabinsk basin | 29,9 | 1,0 | 14,19 |
South Ural basin | 6,6 | 0,7 | 9,11 |
Karaganda basin | 27,6 | 0,8 | 21,12 |
Ekibastuz basin | 32,6 | 0,7 | 18,94 |
Turgai basin | 11,3 | 1,6 | 13,13 |
Kuznetsk basin | 13,2 | 0,4 | 22,93 |
Gorlovsky | 11,7 | 0,4 | 26,12 |
Kuznetsky (open pit mining) | 11,0 | 0,4 | 21,46 |
Kansko-Achinsk basin | 6,7 | 0,2 | 15,54 |
Minusinsky | 17,2 | 0,5 | 20,16 |
Irkutsk | 27,0 | 1,0 | 17,93 |
Buryat | 16,9 | 0,7 | 16, 88 |
Partisan (Suchansky) | 34,0 | 0,5 | 20,81 |
Razdolnensky | 32,0 | 0,4 | 19,64 |
Sakhalin | 22,0 | 0,4 | 17,83 |
oil shale | |||
Estonian slate | 50,5 | 1,6 | 11,94 |
Leningradslanets | 54,2 | 1,5 | 9,50 |
Peat | |||
Rostorf in general | 12,5 | 0,3 | 8,12 |
Other fuels | |||
Firewood | 0,6 | - | 10,24 |
Low-sulfur fuel oil | 0,1 | 0,5 | 40,30 |
Sulphurous fuel oil | 0,1 | 1,9 | 39,85 |
High sulfur fuel oil | 0,1 | 4,1 | 38,89 |
Diesel fuel | 0,025 | 0,3 | 42,75 |
Solar oil | 0,02 | 0,3 | 42,46 |
Natural gas from gas pipelines | |||
Saratov - Moscow | - | - | 35,80 |
Saratov - Gorky | - | - | 36,13 |
Stavropol - Moscow | - | - | 36,00 |
Serpukhov - Leningrad | - | - | 37,43 |
Bryansk - Moscow | - | - | 37,30 |
Promyslovka - Astrakhan | - | - | 35,04 |
Stavropol - Nevinnomyssk - Grozny | - | - | 41,75 |
Table 2.2.2
Average operational efficiency of gas cleaning and dust collection devices
#G0Apparatus, installation | Capture efficiency, % () |
|
solid and liquid particles | gaseous and vapor components |
|
1 | 2 | 3 |
Waste gases from boiler houses | ||
Battery cyclones type BTs-2 | 85 | - |
Battery cyclones based on SEC-24 section | 93 | - |
Smoke exhauster-dust collector DP-10 | 90 | - |
Battery cyclones type TsBR-150U | 93-95 | - |
Electrostatic precipitators | 97-99 | - |
Centrifugal scrubbers TsS-VTI | 88-90 | - |
Wet rod ash collectors VTI | 90-92 | - |
Louvred ash collectors | 75-85 | - |
Group cyclones TsN-15 | 85-90 | - |
Aspiration air from material handling equipment | ||
a) Apparatus and installations for dry cleaning | ||
Dust chambers | 45-55 | - |
Cyclones TsN-15 | 80-85 | - |
Cyclones TsN-11 | 81-87 | - |
Cyclones SDK-TSN-33, SK-TSN-34 | 85-93 | - |
Conical cyclones SIOT | 60-70 | - |
Cyclones VTsNIIOT with reverse cone | 60-70 | - |
Cyclones of Klaipeda OEKDM Gidrodrevprom | 60-90 | - |
Group cyclones | 85-90 | - |
Battery cyclones BC | 82-90 | - |
Bag filters | 99 and above | - |
Mesh filters (for fibrous dust) | 93-96 | - |
Individual units such as ZIL-900, AE212, PA212, etc. | 95 | |
Cyclones LIOT | 70-80 | |
b) Apparatus and installations for wet cleaning | ||
Cyclones with water film TsVP and SIOT | 80-90 | - |
Hollow scrubbers | 70-89 | - |
foam machines | 75-90 | - |
Centrifugal scrubber TsS-VTI | 88-93 | - |
Low-pressure dust collectors KMP | 92-96 | - |
Wet dust collectors with internal circulation type PVM, PV-2 | 97-99 | - |
Venturi pipes type GVPV | 90-94 | - |
Ventilation emissions from chemical and electrochemical processing of metals |
||
Chromic anhydride aerosol cleaning: | ||
Packed scrubbers with horizontal gas flow | 90-95 | - |
fibrous mist eliminators FVG-T | 96-99 | - |
hydraulic filter GPI "Santekhproekt" | 87-90 | - |
foam machines PGP-I | 80-90 | - |
turbulent-contact adsorbers of the TKA type | 80-90 | - |
louvred separator | 85-90 | - |
Purification from vapors of acids and alkalis: | ||
foam machines | - | 80-85 |
absorption-filtering scrubber of NIIOGAZ | 95-98 | 50-60 |
nozzle scrubbers | - | 55-60 |
Two-stage absorbers: | ||
hydrochloric acid vapor | - | 93-95 |
ammonia vapor | - | 20-30 |
chlorine vapor | - | 12-15 |
Ventilation emissions when painting products |
||
Hydraulic filters: | ||
nozzle | 86-92 | - |
cascading | 90-92 | 20-30 |
bubbling-vortex | 94-97 | 40-50 |
Solvent recovery plants (solid adsorption) | - | 92-95 |
Installations for thermal oxidation of solvent vapors | - | 92-97 |
Installations for the catalytic oxidation of solvent vapors | - | 95-99 |
Table 2.2.3
Dependence on the steam capacity of boiler units
#G0Steam capacity of boiler units (t/h) | Meaning |
|||
natural gas, oil | anthracite | brown coal | coal |
|
1 | 2 | 3 | 4 | 5 |
0,5 | 0,08 | 0,095 | 0,155 | 0,172 |
0,7 | 0,085 | 0,10 | 0,163 | 0,18 |
1,0 | 0,09 | 0,105 | 0,168 | 0,188 |
2,0 | 0,095 | 0,12 | 0,183 | 0,20 |
3,0 | 0,098 | 0,125 | 0,192 | 0,21 |
4,0 | 0,099 | 0,13 | 0,198 | 0,215 |
6,0 | 0,1 | 0,135 | 0,205 | 0,225 |
8,0 | 0,102 | 0,138 | 0,213 | 0,228 |
10,0 | 0,103 | 0,14 | 0,215 | 0,235 |
15,0 | 0,108 | 0,15 | 0,225 | 0,248 |
20,0 | 0,109 | 0,155 | 0,23 | 0,25 |
25,0 | 0,11 | 0,158 | 0,235 | 0,255 |
30,0 | 0,115 | 0,16 | 0,24 | 0,26 |
Table 2.2.4
The value of the coefficient depending on the type of furnace and fuel
#G0Fire type | Fuel | |
1 | 2 | 3 |
With fixed grating and manual casting | Brown and black coals | 0,0023 |
Anthracites: | ||
AC and AM | 0,0030 |
|
workstation | 0,0078 |
|
With pneumo-mechanical casters and a fixed grate | Brown and black coals | 0,0026 |
Anthracite ARSH | 0,0088 |
|
With straight chain grate | Anthracite AC and AM | 0,0020 |
With casters and chain grate | Brown and black coals | 0,0035 |
Mine | solid fuel | 0,0019 |
Mine and chain | Peat lump | 0,0019 |
Tilt-and-push | Estonian shales | 0,0025 |
Layered furnaces of domestic heating units | Firewood | 0,0050 |
brown coals | 0,0011 |
|
hard coals | 0,0011 |
|
Anthracite, lean coals | 0,0011 |
|
Chamber furnaces: | ||
steam and hot water boilers | fuel oil | 0,010 |
Natural, associated and coke oven gas | - |
|
household heat generators | natural gas | - |
Light liquid (furnace) fuel | 0,010 |
, g/s (2.2.2)
where: - fuel consumption for the coldest month of the year, t;
is the number of days in the coldest month of the year.
2. Gross carbon monoxide emissions are calculated using the formula: , t/year (2.2.3)
where: - heat loss due to mechanical incompleteness of combustion,% (Table 2.2.5);
- amount of fuel consumed, t/year, thousand m/year;
- output of carbon monoxide during fuel combustion, kg/t, kg/thous. m. (2.2.4)
where: - heat loss due to chemical incompleteness of fuel combustion, % (Table 2.2.5);
- coefficient taking into account the share of heat loss due to chemical incompleteness of fuel combustion:
=1 - for solid fuel,
=0.5 - for gas
\u003d 0.65 - for fuel oil;
- lower calorific value of natural fuel (determined according to Table 2.2.1).
Table 2.2.5
Characteristics of furnaces and boilers of low power
#G0Type of furnace and boiler | Fuel | | |
1 | 2 | 3 | 4 |
Firebox with chain grate | Donetsk anthracite | 0,5 | 13,5/10 |
Mine and chain firebox | Peat lump | 1,0 | 2,0 |
Furnace with pneumo-mechanical casters and straight chain grate | Kuznetsk type coals | 0,5-1 | 5,5/3 |
Donetsk type coals | 0,5-1 | 6/3,5 |
|
brown coals | 0,5-1 | 5,5/4 |
|
Furnace with pneumomechanical casters and reverse chain grate | hard coals | 0,5-1 | 5,5/3 |
brown coals | 0,5-1 | 6,6/4,5 |
|
Furnace with pneumomechanical casters and fixed grate | Donetsk anthracite | 0,5-1 | 13,5/10 |
Brown coals of the type near Moscow | 0,5-1 | 9/7,5 |
|
Brown coals such as Borodino | 0,5-1 | 6/3 |
|
Kuznetsk type coals | 0,5-1 | 5,5/3 |
|
Mine furnace with inclined grate | Firewood, crushed waste, sawdust, lump peat | 2 | 2 |
Fast burning furnace | Firewood, wood chips, sawdust | 1 | 4/2 |
Layered boiler furnace with a steam capacity of more than 2 t/h | Estonian shales | 3 | 3 |
Chamber furnace with solid slag removal | hard coals | 0,5 | 5/3 |
brown coals | 0,5 | 3/1,5 |
|
milled peat | 0,5 | 3/1,5 |
|
chamber furnace | fuel oil | 0,5 | 0,5 |
Gas (natural associated) | 0,5 | 0,5 |
|
Blast furnace gas | 1,5 | 0,5 |
Note. In column 4, higher values - in the absence of means to reduce entrainment, smaller ones - with sharp blast and the presence of entrainment return, as well as for boilers with a capacity of 25-35 t / h.
The maximum single emission of carbon monoxide is determined by the formula: , g/s (2.2.5)
where: is the fuel consumption for the coldest month, i.e.
3. Gross emission of nitrogen oxides is determined by:
, t/year (2.2.6)
where: is a parameter characterizing the amount of nitrogen oxides generated per one GJ of heat, kg/GJ, (determined according to Table 2.2.3) for various types of fuel, depending on the performance of the boiler unit (D);
- coefficient depending on the degree of reduction of nitrogen oxide emissions as a result of the application of technical solutions. For boilers with capacity up to 30 t/h =0.
The maximum one-time release is determined by the formula: , g/s (2.2.7)
4. Gross emission of sulfur oxides is determined only for solid and liquid fuels according to the formula:
, t/year (2.2.8)
where: - sulfur content in the fuel, % (Table 2.2.1);
is the proportion of sulfur oxides bound by the fly ash of the fuel. For Estonian or Leningrad slates it is taken equal to 0.8, for other slates - 0.5; coals of the Kansk-Achinsk basin - 0.2 (Berezovsky - 0.5); peat - 0.15, Ekibastuz - 0.02, other coals - 0.1; fuel oil - 0.2;
- the proportion of sulfur oxides captured in the ash collector.
For dry ash collectors, it is assumed to be 0.
The maximum one-time release is determined by the formula:
, g/s (2.2.9)
5. Calculation of emissions of vanadium pentoxide entering the atmosphere with flue gases during the combustion of liquid fuel is carried out according to the formula:
, kg/year (2.2.10)
where: - the amount of fuel oil consumed per year, t;
- content of vanadium pentoxide in liquid fuel, g/t (in the absence of fuel analysis results, for fuel oil with >0.4% is determined by formula (2.2.11);
- coefficient of vanadium pentoxide settling on the heating surfaces of boilers;
- 0.07 - for boilers with intermediate superheaters, the heating surfaces of which are cleaned in a stopped state;
- 0.05 - for boilers without intermediate superheaters under the same cleaning conditions;
= 0 - for other cases;
- the proportion of solid particles in the products of combustion of liquid fuels captured in devices for cleaning gases from oil-fired boilers (estimated by the average performance of the trapping devices for the year or according to Table 2.2.2).
The content of vanadium pentoxide in liquid fuel is approximately determined by the formula: , g/t (2.2.11)
The calculation of the maximum single release of vanadium is carried out according to the formula: , g/s (2.2.12)
where: - the amount of fuel oil consumed in the coldest month of the year, t;
- the number of days in the billing month.